Aluminium - History

History

Ancient Greeks and Romans used aluminium salts as dyeing mordants and as astringents for dressing wounds; alum is still used as a styptic. In 1761, Guyton de Morveau suggested calling the base alum alumine. In 1808, Humphry Davy identified the existence of a metal base of alum, which he at first termed alumium and later aluminum (see etymology section, below).

The metal was first produced in 1825 in an impure form by Danish physicist and chemist Hans Christian Ørsted. He reacted anhydrous aluminium chloride with potassium amalgam, yielding a lump of metal looking similar to tin. Friedrich Wöhler was aware of these experiments and cited them, but after redoing the experiments of Ørsted he concluded that this metal was pure potassium. He conducted a similar experiment in 1827 by mixing anhydrous aluminium chloride with potassium and yielded aluminium. Wöhler is generally credited with isolating aluminium (Latin alumen, alum), but also Ørsted can be listed as its discoverer. Further, Pierre Berthier discovered aluminium in bauxite ore and successfully extracted it. Frenchman Henri Etienne Sainte-Claire Deville improved Wöhler's method in 1846, and described his improvements in a book in 1859, chief among these being the substitution of sodium for the considerably more expensive potassium. Deville likely also conceived the idea of the electrolysis of aluminium oxide dissolved in cryolite; Charles Martin Hall and Paul Héroult might have developed the more practical process after Deville.

Before the Hall-Héroult process was developed in the late 1880s, aluminium was exceedingly difficult to extract from its various ores. This made pure aluminium more valuable than gold. Bars of aluminium were exhibited at the Exposition Universelle of 1855. Napoleon III of France is reputed to have given a banquet where the most honoured guests were given aluminium utensils, while the others made do with gold.

Aluminium was selected as the material to be used for the 100 ounce (2.8 kg) capstone of the Washington Monument in 1884, a time when one ounce (30 grams) cost the daily wage of a common worker on the project. The capstone, which was set in place on December 6, 1884, in an elaborate dedication ceremony, was the largest single piece of aluminium cast at the time, when aluminium was as expensive as silver.

The Cowles companies supplied aluminium alloy in quantity in the United States and England using smelters like the furnace of Carl Wilhelm Siemens by 1886. Charles Martin Hall of Ohio in the U.S. and Paul Héroult of France independently developed the Hall-Héroult electrolytic process that made extracting aluminium from minerals cheaper and is now the principal method used worldwide. Hall's process, in 1888 with the financial backing of Alfred E. Hunt, started the Pittsburgh Reduction Company today known as Alcoa. Héroult's process was in production by 1889 in Switzerland at Aluminium Industrie, now Alcan, and at British Aluminium, now Luxfer Group and Alcoa, by 1896 in Scotland.

By 1895, the metal was being used as a building material as far away as Sydney, Australia in the dome of the Chief Secretary's Building.

Many navies have used an aluminium superstructure for their vessels; the 1975 fire aboard USS Belknap that gutted her aluminium superstructure, as well as observation of battle damage to British ships during the Falklands War, led to many navies switching to all steel superstructures. The Arleigh Burke class was the first such U.S. ship, being constructed entirely of steel.

Aluminium wire was once widely used for domestic electrical wiring. Owing to corrosion-induced failures, a number of fires resulted.