Explanation of The General Trends
The way the atomic radius varies with increasing atomic number can be explained by the arrangement of electrons in shells of fixed capacity. The shells are generally filled in order of increasing radius, since the negatively charged electrons are attracted by the positively charged protons in the nucleus. As the atomic number increases along each row of the periodic table, the additional electrons go into the same outermost shell; whose radius gradually contracts, due to the increasing nuclear charge. In a noble gas, the outermost shell is completely filled; therefore, the additional electron of next alkali metal will go into the next outer shell, accounting for the sudden increase in the atomic radius.
The increasing nuclear charge is partly counterbalanced by the increasing number of electrons, a phenomenon that is known as shielding; which explains why the size of atoms usually increases down each column. However, there is one notable exception, known as the lanthanide contraction: the 5d block of elements are much smaller than one would expect, due to the shielding caused by the 4f electrons.
The following table summarizes the main phenomena that influence the atomic radius of an element:
| factor | principle | increase with... | tend to | effect on radius |
|---|---|---|---|---|
| electron shells | quantum mechanics | principal and azimuthal quantum numbers | increase atomic radius | increases down each column |
| nuclear charge | attractive force acting on electrons by protons in nucleus | atomic number | decrease atomic radius | decreases along each period |
| shielding | repulsive force acting on outermost shell electrons by inner electrons | number of electron shells | increase atomic radius | reduces the effect of the 2nd factor |
Read more about this topic: Atomic Radius
Famous quotes containing the words explanation of the, explanation of, explanation, general and/or trends:
“Herein is the explanation of the analogies, which exist in all the arts. They are the re-appearance of one mind, working in many materials to many temporary ends. Raphael paints wisdom, Handel sings it, Phidias carves it, Shakspeare writes it, Wren builds it, Columbus sails it, Luther preaches it, Washington arms it, Watt mechanizes it. Painting was called “silent poetry,” and poetry “speaking painting.” The laws of each art are convertible into the laws of every other.”
—Ralph Waldo Emerson (1803–1882)
“To develop an empiricist account of science is to depict it as involving a search for truth only about the empirical world, about what is actual and observable.... It must involve throughout a resolute rejection of the demand for an explanation of the regularities in the observable course of nature, by means of truths concerning a reality beyond what is actual and observable, as a demand which plays no role in the scientific enterprise.”
—Bas Van Fraassen (b. 1941)
“To develop an empiricist account of science is to depict it as involving a search for truth only about the empirical world, about what is actual and observable.... It must involve throughout a resolute rejection of the demand for an explanation of the regularities in the observable course of nature, by means of truths concerning a reality beyond what is actual and observable, as a demand which plays no role in the scientific enterprise.”
—Bas Van Fraassen (b. 1941)
“Any general statement is like a cheque drawn on a bank. Its value depends on what is there to meet it.”
—Ezra Pound (1885–1972)
“Power-worship blurs political judgement because it leads, almost unavoidably, to the belief that present trends will continue. Whoever is winning at the moment will always seem to be invincible.”
—George Orwell (1903–1950)