In organic chemistry, butyl is a four-carbon alkyl radical or substituent group with general chemical formula -C4H9, derived from either of the two isomers of butane.
The isomer n-butane can connect either at one of the two terminal carbon atoms or at one of the two internal carbon atoms, giving rise to two "-butyl" groups:
- Normal butyl or n-Butyl: CH3–CH2–CH2–CH2– (fully systematic name: butyl)
- Secondary butyl or sec-Butyl: CH3–CH2–CH(CH3)– (fully systematic name: 1-methylpropyl)
The second, branched isomer of butane, isobutyl, can connect either at one of the three terminal carbons or at the central carbon, giving rise to another two groups:
- Isobutyl: (CH3)2CH–CH2– (fully systematic name: 2-methylpropyl)
- Tertiary butyl, tert-Butyl or t-butyl: (CH3)3C– (fully systematic name: 1,1-dimethylethyl)
Read more about Butyl: Nomenclature, Some Examples, Etymology, Tert-butyl Effect