Chondrite - Petrologic Types

Petrologic Types

A chondrite's group is determined by its primary chemical, mineralogical, and isotopic characteristics (above). The degree to which it has been affected by the secondary processes of thermal metamorphism and aqueous alteration on the parent asteroid is indicated by its petrologic type, which appears as a number following the group name (e.g., an LL5 chondrite belongs to the LL group and has a petrologic type of 5). The current scheme for describing petrologic types was devised by Van Schmus and Wood in 1967.

The petrologic-type scheme originated by Van Schmus and Wood is really two separate schemes, one describing aqueous alteration (types 1-2) and one describing thermal metamorphism (types 3-6). The aqueous alteration part of the system works as follows:

• Type 1 was originally used to designate chondrites that lacked chondrules and contained large amounts of water and carbon. Current usage of type 1 is simply to indicate meteorites that have experienced extensive aqueous alteration, to the point that most of their olivine and pyroxene have been altered to hydrous phases. This alteration took place at temperatures of 50 to 150 °C, so type 1 chondrites were warm, but not hot enough to experience thermal metamorphism. The members of the CI group, plus a few highly altered carbonaceous chondrites of other groups, are the only instances of type 1 chondrites.

• Type 2 chondrites are those that have experienced extensive aqueous alteration, but still contain recognizable chondrules as well as primary, unaltered olivine and/or pyroxene. The fine-grained matrix is generally fully hydrated and minerals inside chondrules may show variable degrees of hydration. This alteration probably occurred at temperatures below 20 °C, and again, these meteorites are not thermally metamorphosed. Almost all CM and CR chondrites are petrologic type 2; with the exception of some ungrouped carbonaceous chondrites, no other chondrites are type 2.

The thermal metamorphism part of the scheme describes a continuous sequence of changes to mineralogy and texture that accompany increasing metamorphic temperatures. These chondrites show little evidence of the effects of aqueous alteration:

• Type 3 chondrites show low degrees of metamorphism. They are often referred to as unequilibrated chondrites because minerals such as olivine and pyroxene show a wide range of compositions, reflecting formation under a wide variety of conditions in the solar nebula. (Type 1 and 2 chondrites are also unequilibrated.) Chondrites that remain in nearly pristine condition, with all components (chondrules, matrix, etc.) having nearly the same composition and mineralogy as when they accreted to the parent asteroid, are designated type 3.0. As petrologic type increases from type 3.1 through 3.9, profound mineralogical changes occur, starting in the dusty matrix, and then increasingly affecting the coarser-grained components like chondrules. Type 3.9 chondrites still look superficially unchanged because chondrules retain their original appearances, but all of the minerals have been affected, mostly due to diffusion of elements between grains of different composition.

• Types 4, 5, and 6 chondrites have been increasingly altered by thermal metamorphism. These are equilibrated chondrites, in which the compositions of most minerals have become quite homogeneous due to high temperatures. By type 4, the matrix has thoroughly recrystallized and coarsened in grain size. By type 5, chondrules begin to become indistinct and matrix cannot be discerned. In type 6 chondrites, chondrules begin to integrate with what was once matrix, and small chondrules may no longer be recognizable. As metamorphism proceeds, many minerals coarsen and new, metamorphic minerals such as feldspar form.

Some workers have extended the Van Schmus and Wood metamorphic scheme to include a type 7, although there is not consensus on whether this is necessary. Type 7 chondrites have experienced the highest temperatures possible, short of that required to produce melting. Should the onset of melting occur the meteorite would probably be classified as a primitive achondrite instead of a chondrite.

All groups of ordinary and enstatite chondrites, as well as R and CK chondrites, show the complete metamorphic range from type 3 to 6. CO chondrites comprise only type 3 members, although these span a range of petrologic types from 3.0 to 3.8.