In chemistry an eclipsed conformation is a conformation in which two substituents X and Y on adjacent atoms A, B are in closest proximity, implying that the torsion angle X-A-B-Y is 0°. Such a conformation exists in any open chain single chemical bond connecting two sp3 hybridised atoms, and is normally a conformational energy maximum. This maximum is often explained by steric hindrance, but its origins sometimes actually lie in hyperconjugation (as when the eclipsing interaction is of two hydrogen atoms).
In the example of ethane in Newman projection it shows that rotation around the carbon-carbon bond is not entirely free but that an energy barrier exists. The ethane molecule in the eclipsed conformation is said to suffer from torsional strain and by a rotation around the carbon carbon bond to the staggered conformation around 12.5 kJ/mol of torsional energy is released.
Famous quotes containing the word eclipsed:
“The apparent rulers of the English nation are like the imposing personages of a splendid procession: it is by them the mob are influenced; it is they whom the spectators cheer. The real rulers are secreted in second-rate carriages; no one cares for them or asks after them, but they are obeyed implicitly and unconsciously by reason of the splendour of those who eclipsed and preceded them.”
—Walter Bagehot (1826–1877)
“They may bring their fattest cattle and richest fruits to the fair, but they are all eclipsed by the show of men. These are stirring autumn days, when men sweep by in crowds, amid the rustle of leaves like migrating finches; this is the true harvest of the year, when the air is but the breath of men, and the rustling of leaves is as the trampling of the crowd.”
—Henry David Thoreau (1817–1862)