Foaming and Foam Stability
Several conditions are needed to produce foam: there must be mechanical work, surface active components (surfactants) that reduce the surface tension, and the formation of foam faster than its breakdown. To create foam, work (W) is needed to increase the surface area (ΔA):
where γ is the surface tension.
Stabilisation of foam is caused by van der Waals forces between the molecules in the foam, electrical double layers created by dipolar surfactants, and the Marangoni effect, which acts as a restoring force to the lamellas.
Several destabilising effects can break foam down. (i) Gravitation causes drainage of liquid to the foam base, (ii)osmotic pressure causes drainage from the lamellas to the Plateau borders due to internal concentration differences in the foam, while (iii)Laplace pressure causes diffusion of gas from small to large bubbles due to pressure difference. Films can break under disjoining pressure, These effects can lead to rearrangement of the foam structure at scales larger than the bubbles, which may be individual (T1 process) or collective (even of the "avalanche" type).
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Famous quotes containing the words foaming, foam and/or stability:
“Thanks to the morning light,
Thanks to the foaming sea,
To the uplands of New Hampshire,
To the green-haired forest free.”
—Ralph Waldo Emerson (1803–1882)
“Yet ere I can say where—the chariot hath
Passed over them—nor other trace I find
But as of foam after the ocean’s wrath”
—Percy Bysshe Shelley (1792–1822)
“The world can be at peace only if the world is stable, and there can be no stability where the will is in rebellion, where there is not tranquility of spirit and a sense of justice, of freedom, and of right.”
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