Halogen - Group Trends

Group Trends

Like other groups, the candidates of this family show patterns in its electron configuration, especially the outermost shells resulting in trends in chemical behavior:

Z Element No. of electrons/shell
9 fluorine 2, 7
17 chlorine 2, 8, 7
35 bromine 2, 8, 18, 7
53 iodine 2, 8, 18, 18, 7
85 astatine 2, 8, 18, 32, 18, 7

The halogens show a series of trends when moving down the group—for instance, decreasing electronegativity and reactivity, and increasing melting and boiling point.

Halogen Standard Atomic Weight (u) Melting Point (K) Boiling Point (K) Electronegativity (Pauling)
Fluorine 18.998 53.53 85.03 3.98
Chlorine 35.453 171.60 239.11 3.16
Bromine 79.904 265.80 332.00 2.96
Iodine 126.904 386.85 457.40 2.66
Astatine (210) 575.00 610 (?) 2.20

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