Muon - Muonic Atoms

Muonic Atoms

The muon was the first elementary particle discovered that does not appear in ordinary atoms. Negative muons can, however, form muonic atoms (also called mu-mesic atoms), by replacing an electron in ordinary atoms. Muonic hydrogen atoms are much smaller than typical hydrogen atoms because the much larger mass of the muon gives it a much more localized ground-state wavefunction than is observed for the electron. In multi-electron atoms, when only one of the electrons is replaced by a muon, the size of the atom continues to be determined by the other electrons, and the atomic size is nearly unchanged. However, in such cases the orbital of the muon continues to be smaller and far closer to the nucleus than the atomic orbitals of the electrons.

Muonic helium is created by substituting a muon for one of the electrons in helium-4. The muon orbits much closer to the nucleus, so muonic helium can therefore be regarded like an isotope of hydrogen whose nucleus consists of two neutrons, two protons and a muon, with a single electron outside. Colloquially, it could be called "hydrogen 4.1", since the mass of the muon is roughly 0.1 au. Chemically, muonic helium can bond with other atoms, and behaves more like a hydrogen atom than an inert helium atom.

A positive muon, when stopped in ordinary matter, can also bind an electron and form an exotic atom known as muonium (Mu) atom, in which the muon acts as the nucleus. The positive muon, in this context, can be considered a pseudo-isotope of hydrogen with one ninth of the mass of the proton. Because the reduced mass of muonium, and hence its Bohr radius, is very close to that of hydrogen, this short-lived "atom" behaves chemically — to a first approximation — like hydrogen, deuterium and tritium.