Perovskite - Physical Properties

Physical Properties

The sub-metallic to metallic luster, colorless streak, cube like structure along with imperfect cleavage and brittle tenacity are physical properties of perovskite. Colors range from black, brown, gray, orange to yellow. Crystals of perovskite appear as cubes, but are pseudocubic and crystallize in the orthorhombic system. Perovskite crystals have been mistaken for galena; however, galena has a better metallic luster, greater density, perfect cleavage and true cubic symmetry.

Physical properties of interest to materials science among perovskites include superconductivity, magnetoresistance, ionic conductivity, and a multitude of dielectric properties, which are of great importance in microelectronics and telecommunication. Because of the flexibility of bond angles inherent in the perovskite structure there are many different types of distortions which can occur from the ideal structure. These include tilting of the octahedra, displacements of the cations out of the centers of their coordination polyhedra, and distortions of the octahedra driven by electronic factors (Jahn-Teller distortions).

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