Medieval Usage
Scotia was a way of saying "Land of the Gaels"; compare Angli, Anglia; Franci, Francia; Romani, Romania; etc. It originally was used as a name for Ireland, as when Isidore of Seville in 580 CE says "Scotia and Hibernia are the same country" (Isidore, lib. xii. c. 6)", but the connotation is still ethnic. This is how it is used, for instance, by King Robert I of Scotland and Domhnall Ua Néill during the Scottish Wars of Independence, when Ireland was called Scotia Maior, and Scotland Scotia Minor.
After the fall of the Roman Empire, the coasts on the Irish Sea were raided by pirates either from Eastern Ireland or Western Scotland. They did gain power in Western Scotland, originated new small kingdoms, and reinforced the idea of a common origin and that Scotland was somehow populated (or re-populated) by Gaelic Irish.
However, after the 11th century, Scotia, when Scotland was already stabilised as a nation-kingdom, was used mostly for northern Great Britain, and in this way became the fixed designation. As a translation of Alba, Scotia could mean both the whole Kingdom belonging to the rex Scottorum, or just Scotland north of the Forth.
In the bureaucratic world of the Roman Catholic Church, Pope Leo X eventually granted Scotland exclusive right over the word, and this led to Anglo-Scottish takeovers of continental Gaelic monasteries (e.g. the Schottenklöster).
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