Triiodide - Preparation

Preparation

The following endergonic equilibrium gives rise to the triiodide ion:

I2 + Iāˆ’ ā‡Œ I3āˆ’

In this reaction, iodide is viewed as a Lewis base, and the iodine is a Lewis acid. The process is analogous to the reaction of S8 with sodium sulfide, except that the higher polyiodides have branched structures.

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