Xylene - Properties

Properties

Xylenes encompass three isomers of dimethylbenzene. The isomers are distinguished by the designations ortho- (o-), meta- (m-), and para- (p-), which specify to which carbon atoms (of the benzene ring) the two methyl groups are attached. Counting the carbon atoms from one of the ring carbons bonded to a methyl group, and counting towards the second ring carbon bonded to a methyl group, the o- isomer has the IUPAC name of 1,2-dimethylbenzene, the m- isomer has the IUPAC name of 1,3-dimethylbenzene, and the p- isomer has the IUPAC name of 1,4-dimethylbenzene.

Some chemical and physical properties differ from isomer to isomer. The melting point ranges from −47.87 °C (−54.17 °F) (m-xylene) to 13.26 °C (55.87 °F) (p-xylene). The boiling point for each isomer is around 140 °C (284.00 °F). The density of each is around 0.87 g/mL (7.26 lb/U.S. gallon or 8.72 lb/imp gallon) and thus is less dense than water. Xylene in air can be smelled at 0.08 to 3.7 parts of xylene per million parts of air (ppm) and can begin to be tasted in water at 0.53 to 1.8 ppm.

Xylene Isomers
General
Common name Xylenes o-Xylene m-Xylene p-Xylene
Systematic name Dimethylbenzenes 1,2-Dimethylbenzene 1,3-Dimethylbenzene 1,4-Dimethylbenzene
Other names Xylols o-Xylol;
Orthoxylene
m-Xylol;
Metaxylene
p-Xylol;
Paraxylene
Molecular formula C8H10, C6H4(CH3)2 or C6H4C2H6
SMILES Cc1c(C)cccc1 Cc1cc(C)ccc1 Cc1ccc(C)cc1
Molar mass 106.16 g/mol
Appearance clear, colorless liquid
CAS number
Properties
Density and phase 0.864 g/mL, liquid 0.88 g/mL, liquid 0.86 g/mL, liquid 0.86 g/mL, liquid
Solubility in water practically insoluble
Soluble in non-polar solvents such as aromatic hydrocarbons
Melting point −47.4 °C (−53.3 °F; 226 K) −25 °C (−13 °F; 248 K) −48 °C (−54.4 °F; 225 K) 13 °C (55.4 °F; 286 K)
Boiling point 138.5 °C (281.3 °F; 412 K) 144 °C (291.2 °F; 417 K) 139 °C (282.2 °F; 412 K) 138 °C (280.4 °F; 411 K)
Viscosity 0.812 cP at 20 °C (68 °F) 0.62 cP at 20 °C (68 °F) 0.34 cP at 30 °C (86 °F)
Hazards
MSDS Xylenes o-Xylene m-Xylene p-Xylene
EU Classification Harmful (Xn)
NFPA 704 3 2 0
Flash point 30 °C (86 °F) 17 °C (63 °F) 25 °C (77 °F) 25 °C (77 °F)
R/S statement R10, R20/21, R38: (S2), S25
RTECS number ZE2450000 ZE2275000 ZE2625000
Supplementary data page
Structure & properties n, εr, etc.
Thermodynamic data Phase behaviour
Solid, liquid, gas
Spectral data UV, IR, NMR, MS
Related compounds
Related aromatic
hydrocarbons
toluene, mesitylene, benzene, ethylbenzene
Related compounds xylenols - types of phenols

Xylenes form azeotropes with water and a variety of alcohols. With water the azeotrope consists of 60% xylenes and boils at 90 °C. As with many alkylbenzene compounds, xylenes form complexes with various halocarbons. The complexes of different isomers often have dramatically different properties from each other.

Read more about this topic:  Xylene

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