Octane rating or octane number is a standard measure of the performance of a motor or aviation fuel. The higher the octane number, the more compression the fuel can withstand before detonating. In broad terms, fuels with a higher octane rating are used in high-compression engines that generally have higher performance. In contrast, fuels with low octane numbers (but high cetane numbers) are ideal for diesel engines. Use of gasolines with low octane numbers may lead to the problem of engine knocking.
Read more about Octane Rating: Principles, Examples of Octane Ratings, Effects of Octane Rating, Regional Variations